热活化-Na_2CO_3改性浮选尾煤基吸附剂对Pb(Ⅱ)的吸附性能研究Study on Pb(Ⅱ) adsorption performance of flotation tail coal modified by thermal activation combined with Na_2CO_3
何梓豪;王磊;
摘要(Abstract):
以浮选尾煤为原料,通过热处理联合Na_2CO_3改性的方法制备了浮选尾煤基吸附剂(TC-CN),采用XRD、FTIR、SEM对吸附剂的表面化学、微观形貌进行表征,并研究了TC-CN对Pb(2+)的吸附性能。结果表明:TC-CN的颗粒均匀化和堆积作用促进了孔隙的增加,保证了吸附剂对Pb(2+)的吸附性能。结果表明:TC-CN的颗粒均匀化和堆积作用促进了孔隙的增加,保证了吸附剂对Pb(2+)的高吸附能力;常温25℃下TC-CN的最佳试验条件:投加量4 g/L、废水初始pH为6、处理时间120 min,对200 mg/L Pb(2+)的高吸附能力;常温25℃下TC-CN的最佳试验条件:投加量4 g/L、废水初始pH为6、处理时间120 min,对200 mg/L Pb(2+)的吸附率为99.3%,适当提高吸附温度效果更好;TC-CN对Pb(2+)的吸附率为99.3%,适当提高吸附温度效果更好;TC-CN对Pb(2+)的吸附过程为自发的吸热过程,以化学吸附为主,最大吸附容量达到65.5 mg/g。研究结果对综合利用浮选尾煤,实现“以废治废”提供了可行的途径。
关键词(KeyWords): 尾煤;吸附剂;铅离子;吸附性能
基金项目(Foundation):
作者(Authors): 何梓豪;王磊;
DOI: 10.16200/j.cnki.11-2627/td.2022.06.017
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